===============SECTION III HAZARDOUS INGREDIENTS============
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM: HEALTH FLAMMABILITY REACTIVITY
2 1 2
INGREDIENT WT.% TLV SOURCE IDLH VAPOR LEL
ppm mg/m3 PRESS.
Bisphenol A Epoxy 60-90% not established TWA/ACGIH N/A nil N/A
(CAS 55818-57-0) not established FEDERAL PEL
not established STEL/ACGIH
Oligomer blend 10-40% not established N/A nil N/A
(proprietary)
================SECTION IV PHYSICAL DATA====================
BOILING RANGE: 293 - 410°F PERCENT VOLATILE BY VOLUME: negligible
SPECIFIC GRAVITY: 1.1 EVAPORATION RATE (n-Bu Ac = 1): nil
PH 6.8 to 7.2 VAPOR PRESSURE (mm HG @ 68°F): nil
VOC Content: nil
APPEARANCE AND ODOR: Clear Viscous solution, acrylic odor
SOLUBILITY IN WATER: negligible
==============SECTION V FIRE AND EXPLOSION DATA=============
FLASH POINT: 200°F / 93°C SETAFLASH OSHA CLASSIFICATION: N/DA
FLAMMABLE LIMITS % BY VOLUME IN AIR @ 212°F:
LOWER EXPLOSION LIMIT - n/a
UPPER EXPLOSION LIMIT - n/a
SECTION V (cont.)
• EXTINGUISHING MEDIA: Use foam, carbon dioxide or chemical fire fighting.
• UNUSUAL FIRE AND EXPLOSION HAZARDS: High temperatures / inhibitor depletion /
accidental impurities / exposure to radiation / strong oxidizers - may cause spontaneous
polymerization which will generate heat/pressure. Closed containers may rupture during
spontaneous polymerization.
• SPECIAL FIRE FIGHTING PROCEDURES: The use of self-contained breathing apparatus is
recommended for fire-fighters. Water spray may be used for cooling containers.
===============SECTION VI HEALTH HAZARD DATA==============
THRESHOLD LIMIT VALUE: see section III
EFFECTS OF OVEREXPOSURE:
• EYES: Minor to moderate irritation, redness, tearing and blurred vision.
• SKIN: Some acrylate/methacrylate materials can be absorbed through the skin. Although no
human or animal health data are known to exist, the potential for skin absorption does exist.
This material is expected to be a skin irritant and may be cause allergic reaction
(sensitization) upon repeated exposure to susceptible individuals.
• INHALATION: No significant signs or symptoms indicative of any health hazard are
expected to occur at standard conditions due to low volatility of this material.
• INGESTION: Although no appropriate human or animal health effects data are known to
exist, this material is expected to be a slight ingestion hazard.
• OTHER HEALTH EFFECTS: This material or its emissions may induce an allergic or
sensitization reaction and thereby aggravate systemic disease.
EMERGENCY AND FIRST AID PROCEDURES
• EYES - Flush with clean, warm water for at least 15 minutes occasionally lifting eyelids.
• SKIN - Remove contaminated clothing. Wash affected areas with soap and water.
• INHALATION- Remove to fresh air. Apply artificial respiration or administer oxygen if
necessary. Call a physician immediately.
• INGESTION - Keep person warm, quiet. Get immediate medical attention. Do not induce
vomiting - risk of damage to lungs exceeds poisoning risk. Obtain emergency medical
attention.
======================SECTION VII REACTIVITY DATA=======================
STABILITY: Stable under normal conditions. Avoid exposure to excessive heat.
Exposure of resin to direct sunlight or UV-A light source will cause rapid
polymerization (hardening) of resin. Only the exposed surface areas will harden
although the heat generated can cause further spontaneous polymerization.
VII CONTINUED
INCOMPATIBILITY: Avoid contact with strong mineral acids, peroxides,
polymerization catalysts and radiation. Do not freeze (inhibitor can separate for
monomer). If freezing occurs, heat and mix to redistribute the inhibitor.
Oxygen is a polymerization inhibitor and anaerobic conditions will favor
spontaneous polymerization. Maintain head space in storage.
HAZARDOUS POLYMERIZATION: Can occur.
=============SECTION VIII SPILL OR LEAK PROCEEDURES=========
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Cover spill with inert absorbent material and shovel into container. Remove
container to a safe area and seal. Wash spill area with strong detergent and
water solution; rinse with water but minimize dispersion and collect.
WASTE DISPOSAL METHOD:
Waste disposal must be disposed of in accordance with federal, state, and local
environmental regulatory controls. Waste is not an RCRA hazardous waste
however, contaminated product/soil/water may be RCRA/OSHA hazardous
waste due to potential for internal heat generation. Dilute aqueus waste may
biodegrade.
===========SECTION IX SPECIAL PROTECTION INFORMATION=======
PROTECTIVE GLOVES: Polyvinyl alcohol gloves.
EYE PROTECTION: Splash goggles.
==================SECTION X TRANSPORTATION===============
DOT HAZARD CLASS - Not Regulated
DOT PROPER SHIPPING NAME - N/A
UN NUMBER - N/A |
|
